| 氯柱硼镁石在盐酸溶液中溶解及相转化平衡溶液的振动光谱分析 |
| Vibrational Spectroscopic Analysis of Saturated Borate Aqueous Solution of Chloropinnoite in HCl(aq) |
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| 摘要: |
| 关键词: 差示FT-IR光谱 Raman光谱 饱和硼酸盐溶液 氯柱硼镁石 盐酸 |
| 基金项目: |
| Abstract: The FT-IR difference spectroscopy and the Raman spectroscopy were used to identify the polyborate ions in saturated aqueous solutions during dissolution and transformation of 2MgO·2B2O3·MgCl2·14H2O in different HCl solutions at 30℃. The assignments of the recorded IR-Spectroscopic frequencies and Raman shift of the borate aqueous solution are given. The existing forms of polyborate anions in saturated aqueous solution and their inter-action have been discussed. The relationships between the existing forms of polyborate anions and the crystallizing solid phases have been gained. |
| Keywords: FT-IR difference spectra Raman spectra saturated borate solution chloropinnoite hydrochloric acid |
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| 全文下载次数: 1946 |
| 高 波,刘志宏,李淑妮,胡满成,夏树屏.氯柱硼镁石在盐酸溶液中溶解及相转化平衡溶液的振动光谱分析[J].无机化学学报,2003,19(9):1015-1018. |
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