| 配合物[Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]的合成及晶体结构 | |||||||
| Synthesis and Crystal Structure of the Complex [Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]2 | |||||||
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| 关键词: 配合物 合成 晶体结构 | |||||||
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| Abstract: The new complex [Ce(CH2=C(CH3)COO)2(NO3)(Phen)]2 was prepared in ethanol-aqueous solution with 8-hydroxyquinoline as the acidity regulator. Its crystal structure was determined by X-ray diffraction analysis. The title complex is triclinic, space group P1, a=1.00832(3)nm, b=1.02858(8)nm, c=1.12350(8)nm, α=113.9250(10)°, β=103.8210(10)°, γ=81.4650(10)°, V=1.03252(14)nm3, Z=1, Dc=1.700g·cm-3, F(000)=522. The coordination number of Ce3+ is nine. CCDC: 211278. | |||||||
| Keywords: complex synthesis crystal structure | |||||||
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| 咸春颖,林 苗.配合物[Ce(CH2=C(CH3)COO)2(NO3)(Bipy)]的合成及晶体结构[J].无机化学学报,2003,19(9):1030-1032. | |||||||
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