| 银离子与聚酰胺-胺型树形高分子配位作用的研究 |
| Study on the Complexation between Poly(amidoamine) Dendrimers and Silver Ion |
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| 摘要: |
| 关键词: PAMAM树形高分子 银离子 分光光度法 配位作用 |
| 基金项目: |
| Abstract: The complexation between poly(amidoamine) (PAMAM) dendrimers and silver ion was studied in this paper. The results showed that generations and surface groups of dendrimers， reaction time， pH value， mole ratio of Ag+/PAMAM dendrimers， as well as reaction temperature strongly influence complexation between Ag+ and PAMAM dendrimers. The maximum complexing number of Ag+ that amino-， hydroxyl- and carboxylate- terminated PAMAM dendrimers could bind has been obtained. It has been found that the measured value of amino- and hydroxyl- ter-minated PAMAM is almost similar to the theory value， but to carboxylate- terminated PAMAM， there is a dis-crepancy between the measured value and theory value because of the electrostatic interaction between the silver ion and carboxyl group. |
| Keywords: PAMAM dendrimers silver ion spectrophotometric method complexation |
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| 李国平,罗运军,徐厚才,崔艳霞,谭惠民.银离子与聚酰胺-胺型树形高分子配位作用的研究[J].无机化学学报,2003,19(11):1212-1216. |
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