| 一种新型多孔道配位聚合物[La(C8H6NO2)3]n的合成及晶体结构表征 |
| Synthesis and Crystal Structure of A Novel Porous Coordination Polymer [La(C8H6NO2)3]n |
|
| 摘要: |
| 关键词: 3-(3-吡啶基)丙烯酸根 多孔道配位聚合物 水热合成 单晶结构 |
| 基金项目: |
| Abstract: A novel porous coordination polymer [La(C8H6NO2)3]n was synthesized by hydrothermal reaction of flexible ligands 3-(3-pyridyl)acrylate and La(NO3)3·6H2O. The structure was characterized by elemental analysis， IR spectroscopy and X-ray single crystal diffraction. X-ray single crystal analysis reveals the structure consists of [La(C8H6NO2)3]n. It crystallizes in monoclinic crystal system with space group P2(1)/c. Crystallographic date: a=0. 7889(3)nm， b=2.5916(9)nm， c=1.1489(4)nm， α=90.00°， β=95.219(6)°， γ=90.00°， V=2.3393(15)nm3， Z=4， Dc=1.656g·cm-3， μ=1.871mm-1， F(000)=1152， R1=0.0328， wR2=0.0522. CCDC: 211700. |
| Keywords: 3-(3-pyridyl)acrylate porous coordination polymer hydrothermal synthesis crystal structure |
| |
| 摘要点击次数: 1127 |
| 全文下载次数: 1522 |
| 周秋香,王延吉,赵新强,岳 琳.一种新型多孔道配位聚合物[La(C8H6NO2)3]n的合成及晶体结构表征[J].无机化学学报,2003,19(11):1245-1248. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
