| 具有梯形结构钴(Ⅱ)配位聚合物的合成及晶体结构(英文) |
| Synthesis and Crystal Structure of a Novel Cobalt(Ⅱ) Coordination Polymer with Molecular Ladder Structure |
| 作者 | 单位 | | 吴杰颖 | 安徽大学化学化工学院,合肥 230039 | | 潘月礼 | 安徽大学化学化工学院,合肥 230039 | | 张宣军 | 中国科学技术大学化学系,合肥 230026 | | 张明亮 | 安徽大学化学化工学院,合肥 230039 | | 田玉鹏 | 安徽大学化学化工学院,合肥 230039；南京大学配位化学国家重点实验室,南京 210093 | | FUN Hoong-Kun | X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM , Penang, Malaysia |
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| 摘要: |
| 关键词: 钴配合物 梯形分子 咔唑乙酸 4,4′-联吡啶 |
| 基金项目: |
| Abstract: Co(NO3)2, N-carbazolyacetic acid and 4,4′-bipyridyl can give rise to a novel coordination polymer [CO2(Cabo)2(NO3)2(4,4′-bipy)2]n using a fritted U-tube. Single crystal X-ray diffraction displays in the complex, each Co(Ⅱ) is six-coordinated by two N atoms from different 4,4′-bipyridyl ligands, two O atoms of the bridge from two N-carbazolyacetic acid and two O atoms of one nitrate anion to form a distorted octahedral. Two O atoms of the carboxyl group act as bridge to link two Co(Ⅱ) atoms. The resulting structure is a ladder polymer. CCDC: 211713. |
| Keywords: cobalt complex molecular ladder N-carbazolyacetic acid 4′4-bipyridyl |
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| 吴杰颖,潘月礼,张宣军,张明亮,田玉鹏,FUN Hoong-Kun.具有梯形结构钴(Ⅱ)配位聚合物的合成及晶体结构(英文)[J].无机化学学报,2003,19(12):1347-1350. |
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