Cd2Ge7O16中Tb的长余辉发光特性
Long Afterglow Property of Cd2Ge7O16∶Tb3+
作者单位
易守军 暨南大学化学系广州 510632 
刘应亮 暨南大学化学系广州 510632 
张静娴 暨南大学化学系广州 510632 
袁定胜 暨南大学化学系广州 510632 
容建华 暨南大学化学系广州 510632 
黄浪欢 暨南大学化学系广州 510632 
摘要: 本文研究了Cd2Ge7O16∶Tb3+材料的发光及其长余辉性质。指出Tb3+的发光是该离子的 5D3- 7DJ5D4- 7DJ两种跃迁产生的;随着掺杂浓度的增加 5D4- 7DJ跃迁增强,发光颜色由蓝变绿。并把该材料的长余辉性质归结为基质结构中有电子陷阱和空穴陷阱。提出余辉机理模型。
关键词: Cd2Ge7O16∶Tb3+ 长余辉 发光机理
基金项目: 
Abstract: Luminescence and long afterglow property of Cd2Ge7O16∶Tb3+ are investigated in the paper. It is shown that luminescence of Cd2Ge7O16∶Tb3+ is due to the 5D3- 7DJ, 5D4- 7DJ transitions of Tb3+ ions. With the increasing of Tb3+ concentration, the intensity of the 5D3- 7DJ emission is decreased, while the intensity of the 5D4- 7DJ emission is increased. The color of Cd2Ge7O16∶Tb3+ is becoming green increasely. Long afterglow property of Cd2Ge7O16∶Tb3+ is due to the electron trap and hole trap of Cd2Ge7O16:Tb3+. We create a model of afterglow mechanism.
Keywords: Cd2Ge7O16∶Tb3+ long afterglow luminescence mechanism
 
摘要点击次数:  942
全文下载次数:  1628
易守军,刘应亮,张静娴,袁定胜,容建华,黄浪欢.Cd2Ge7O16中Tb的长余辉发光特性[J].无机化学学报,2004,20(3):247-250.
查看全文  查看/发表评论  下载PDF阅读器
Support information: