Abstract: The one-dimensional chain self-assembled coordination polymer, [Cd(SCN)2(POM)2]n(where POM is 3-methyl-4-nitropyridine-N-oxide), was synthesized and characterized. The crystal data for the title coordination polymer: monoclinic, space group P21/c, a = 1.182 3(1) nm, b = 0.591 1(1) nm, c = 1.419 2(1) nm, β = 102.875(1)°, Z=2, μ = 1.391 mm-1, final R1 = 0.062 8, wR2 = 0.145 2. The coordination polymer exhibits a strong fluorescent emission band at ca. 518 nm. CCDC: 211506. |
冯小军,杨家祥,于文涛,Fun Hoong-Kun,吴杰颖,田玉鹏.一种新的配位聚合物[Cd(SCN)2(POM)2]n的合成和晶体结构(英)[J].无机化学学报,2004,20(4):403-406. |