LiCoO2对LiMn2O4改性过程的研究
Studies on Process of LiMn2O4 Modified by LiCoO2
作者单位
卢世刚 北京有色金属研究总院矿冶所北京 100088 
李明勋 北京有色金属研究总院矿冶所北京 100088 
黄松涛 北京有色金属研究总院矿冶所北京 100088 
蔡振平 北京有色金属研究总院矿冶所北京 100088 
颜广炅 北京有色金属研究总院矿冶所北京 100088 
金维华 北京有色金属研究总院矿冶所北京 100088 
摘要: 
关键词: 锂离子电池 尖晶石LiMn2O4 改性过程
基金项目: 
Abstract: Modified lithium manganese oxides were prepared by using LiMn2O4 and LiCoO2 as precursors by solid state reaction. A study has been carried out by TG-DSC, XRD and FTIR to analyze the reaction process and structural characterization of products. The results showed that the LiMn2O4 reacted chemically with LiCoO2 at high temperature. Li and Co atom could insert into the LiMn2O4 crystal lattice and obtained the Cobalt-Doped spinel compound. The results of constant-current cyclic test showed that the cyclic stability of the products are increased with the amount of doped LiCoO2, while their initial capacity is decreased.
Keywords: lithium-ion battery spinel LiMn2O4 modification process
 
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卢世刚,李明勋,黄松涛,蔡振平,颜广炅,金维华.LiCoO2对LiMn2O4改性过程的研究[J].无机化学学报,2004,20(4):455-458.
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