| N，N′-双(2-吡啶乙基)二硫代草酰胺根桥联的三核铜(Ⅱ)配合物的合成及性质 |
| Syntheses and Properties of Trinuclear Copper(Ⅱ) Complexes Bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate |
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| 摘要: |
| 关键词: 二硫代草酰胺桥联配体 三核铜(Ⅱ)配合物 磁性 |
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| Abstract: Two Trinuclear copper(Ⅱ) complexes bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate, [Cu3L2](ClO4)2 (1) and [Cu3L2](NO3)2 (2) (H2L=N,N′-Bis(2-pyridylethyl)-Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV-Visible spectra, conductance and EPR spectra. The variable temperature magnetic susceptibility for complex 1 has been measured in the temperature range of 1.5～298 K. Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator：(?), S1=S2=S3=1/2, giving the magnetic exchange parameters of 2J=-221.6 cm-1 and 2j=-15.8 cm-1. This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu(Ⅱ) ions. |
| Keywords: dithiooxamide bridging ligand trinuclear copper(Ⅱ) complex magnetic properties |
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| 崔建中,程 鹏,廖代正,姜宗慧,阎世平,王耕霖.N，N′-双(2-吡啶乙基)二硫代草酰胺根桥联的三核铜(Ⅱ)配合物的合成及性质[J].无机化学学报,2004,20(6):743-747. |
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