| 阴离子对构筑锌的肼配位卤族化合物的影响 |
| The Stabilizing Effect of Anion on the Construction of Hydrozine Bridged Znic Halides Single Crystals |
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| 摘要: |
| 关键词: 阴离子 氢键 晶体结构 |
| 基金项目: |
| Abstract: A series of hydrozine bridged metal halides single crystals were synthesized. Among them were [Zn(N2H4)2F2]·2H2O and [Zn(N2H4)2F]·Cl, the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with [Zn(N2H4)2Cl2]·2H2O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains. CSD: 413707, 1; 413708, 2. |
| Keywords: anion hydrogen bond crystal structure |
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| 董亚杰,王如骥,彭 卿,李亚栋.阴离子对构筑锌的肼配位卤族化合物的影响[J].无机化学学报,2004,20(7):819-823. |
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