| 配位聚合物{[Co(4,4′-bpy)(H2O)4](Fum)·4H2O}n的合成和晶体结构 |
| Synthesis and Crystal Structure of Coordination Polymer {[Co(4,4′-bpy)(H2O)4](Fum)·4H2O}n |
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| 摘要: |
| 关键词: 钴(Ⅱ)配合物 配位聚合物 晶体结构 |
| 基金项目: |
| Abstract: The complex {[Co(4,4′-bpy)(H2O)4](Fum)·4H2O}n(where 4,4′-bpy = 4,4′-bipyridine and Fum = fumarate) was synthesized and characterized by X-ray diffraction. The complex consists of one-dimensional chains containing cobalt(Ⅱ) ions bridged by 4,4′-bpy molecules. The six-coordination of Co2+ is achieved by means of four water molecules. The fumarate is not coordinated to cobalt ion while it forms hydrogen bonds with coordinated and non-coordinated water molecules and extends the structure into three-dimensional hydrogen bonding network. CCDC: 190488. |
| Keywords: Co(Ⅱ) complex coordination polymer crystal structure |
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| 摘要点击次数: 1536 |
| 全文下载次数: 1895 |
| 沈 良,王华彤,张义建.配位聚合物{[Co(4,4′-bpy)(H2O)4](Fum)·4H2O}n的合成和晶体结构[J].无机化学学报,2004,20(7):857-859. |
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