| 中性铜(Ⅰ)卤结构单元及其配位聚合物化学 |
| Structural Units and Coordination Polymer Chemistry of Neutral Copper(Ⅰ) Halide Cluster |
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| 摘要: 铜(Ⅰ)卤簇合物的结构化学极其丰富多彩。一方面，以单齿或是多齿螯合型有机配体为辅助配体，铜(Ⅰ)卤自身可形成多种结构类型的孤立的簇或是低聚物，0维的如菱形的二聚体、立方烷型的或是椅式的四聚体，一维的如锯齿链或是楼梯链等等。若有机配体具有桥联性质，将桥联孤立的簇或是低聚物形成高维聚合物。本文以文献工作为主，结合自身工作，介绍有关中性铜(Ⅰ)卤簇化合物在结构方面的发展概况。 |
| 关键词: 中性 铜(Ⅰ)卤 簇合物 配位聚合物 有机桥联配体 |
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| Abstract: Copper halide clusters show a variety of frameworks in the structure chemistry. On one hand, with the monodentate or bidentate chelate organic ligands as the ancillary ones, copper(Ⅰ) halides can form oligomeric (normally dimers or tetramers) and polymeric (zigzag or staircase chains) frameworks themselves. On the other hand, once the ligands possess bridging nature, these discrete clusters, 1-dimensional or 2-dimensional polymers will be further propagated into high-dimensional sheets or networks. Based on the literature and our group’s works, this article introduces mainly the evolutive survey of copper(Ⅰ) halide clusters in the structure chemistry. |
| Keywords: neutral copper(Ⅰ) halide cluster coordination polymer organic bridging ligand |
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| 于杰辉,别海英,徐吉庆,王铁钢.中性铜(Ⅰ)卤结构单元及其配位聚合物化学[J].无机化学学报,2004,20(11):1249-1256. |
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