| 一维链配位聚合物[Mn(acacen){N(CN)2}]n的合成、结构和性质的研究(英) |
| Synthesis, Structure and Property of One-dimensional Chain Coordination Polymer [Mn(acacen){N(CN)2}]n |
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| 摘要: |
| 关键词: 晶体结构 一维链 锰配合物 二氰氨基 |
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| Abstract: The manganese(Ⅲ) complex [Mn(acacen){N(CN)2}]n [H2acacen=bis(acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligand μ1,5-[N(CN)2]- linking [Mn(acacen)] moiety. The magnetic property of the compound (75～300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940. |
| Keywords: crystal structure one-dimensional chain manganese complex dicyanamide |
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| 王寿武,周俊慧,李宝龙,张 勇.一维链配位聚合物[Mn(acacen){N(CN)2}]n的合成、结构和性质的研究(英)[J].无机化学学报,2004,20(12):1463-1466. |
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