| 新型三齿含膦配体的Ni(Ⅱ)配合物的合成和晶体结构 |
| Synthesis and Crystal Structure of a New Tridentate Ni(Ⅱ) Complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2 |
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| 摘要: |
| 关键词: 三齿配体 镍配合物 晶体结构 合成 |
| 基金项目: |
| Abstract: A new tridentate Ni(Ⅱ) complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2 was synthesized by the reaction of a new ligand Ph2(o-Ph-N-C7H7N)]PO with NiCl2 in CH3CH2OH. The complex was characterized by X-ray single crystal diffraction. The crystal structure of the complex belongs to monoclinic space group P22/n, a=1.259 28(9) nm, b=1.201 24(8) nm, c=2.039 03(14) nm, V=3.016 8(4) nm-3, Z=4, and R2=0.047 1, wR2=0.120 5. And a molecular CH2Cl2 is filled in the crystal structure. CCDC: 241832. |
| Keywords: tridentate ligand Ni complex crystal structure synthesis |
| 投稿时间：2004-04-06 修订日期：2004-10-07 |
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| 程林,欧阳超琴,杨玲.新型三齿含膦配体的Ni(Ⅱ)配合物的合成和晶体结构[J].无机化学学报,2005,21(1):70-72. |
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