| Abstract: The lead iodide adduct [(Pb2I5)(L-H+)·2DMF]n(L=piperazine) has been prepared by self-assembly and structurally characterized. It presents one dimensional structure and crystallizes in Triclinic, P1 space group with the crystal cell parameter: a=0.922 06(18) nm, b=1.237 5(3) nm, c=1.297 2(3) nm, α=99.05(3)°, β=102.98(3)°, γ=105.30(3)°, and V=1.353 8(6) nm3, Z=2, Dc=3.078 Mg·m-3, μ(Mo Kα)=18.127 mm-1, F(000)=1 085, chemical formula C16H43N8O4Pb4I10 and Mr=2 509.39, the final R=0.053 3 and wR=0.146 4 for 3 889 observed reflections with I>2σ(I). CCDC: 250760. |
| 李浩宏,陈之荣,黄长沧,赵斌,肖荣平,倪朝霞.一种新颖一维铅碘聚合物[(Pb2I5)(L-H+)·2DMF]n (L=Piperazine)的自组装合成和晶体结构(英)[J].无机化学学报,2005,21(1):83-86. |
