双取代单酰胺与硝酸铀酰萃合物的制备与表征
Preparation and Characterization of Extracted Species of Uranyl Nitrate with Disubstituted Monoamides
作者单位
孙国新 济南大学化学化工学院济南 250022 
于涛 济南大学化学化工学院济南 250022 
崔玉 济南大学化学化工学院济南 250022 
张振伟 济南大学化学化工学院济南 250022 
李业新 济南大学化学化工学院济南 250022 
摘要: 合成了系列双取代单酰胺萃取剂,利用萃取方法获得了与硝酸铀酰的萃合物。利用元素分析、红外光谱、1H NMR和13C NMR对萃合物进行了表征。结合实验数据初步探讨了萃合物的结构、萃取剂的结构与性能以及萃取体系的三相等问题。
关键词: 单酰胺  硝酸铀酰  萃合物  结构  表征
基金项目: 
Abstract: A series of disubstituted monoamides extractants were synthesized and their extracted species with uranyl nitrate were obtained by extraction method. The foregoing extracted species were characterized by elemental analysis, infrared spectra, 1H NMR and 13C NMR. The structure of the extracted species, the relationship between extractant structure and extractability, and also the third phase formed in the extraction systems were discussed primarily based on the experimental data.
Keywords: monoamide  uranyl nitrate  extracted species  structure  charaterization
投稿时间:2004-07-12 修订日期:2004-11-26
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孙国新,于涛,崔玉,张振伟,李业新.双取代单酰胺与硝酸铀酰萃合物的制备与表征[J].无机化学学报,2005,21(3):363-368.
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