| 金(Ⅲ)与杯[4]乙酯合钠(Ⅰ)超分子化合物: [Na(C60H80O12)]+[Au(SCN)4]-的合成、结构及性能 |
| Synthesis，Crystal Structure and Characterization of a Novel Super Molecule [Na(C60H80O12)]+[Au(SCN)4]- |
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| 摘要: |
| 关键词: 杯[4]芳烃 金(Ⅲ) 超分子化合物 合成 晶体结构 |
| 基金项目: |
| Abstract: A novel super molecule [Na(C60H80O12)]+[Au(SCN)4]- was obtained by extraction of calix[4] arene (L) for an aqueous solution containing [AuCl4]-, and NaCl into CH2Cl2. The crystal structure and properties of the title super molecule were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragonal system with space group P4/n and the unit cell parameters were as follows: a=2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices [I>2σ(I)]: R1=0.048 5, wR2=0.106 1. CCDC: 243229. |
| Keywords: calix[4]arene gold(Ⅲ) association complex synthesis crystal structure |
| 投稿时间：2004-07-12 修订日期：2004-11-18 |
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| 付勇,徐琰,宋毛平,吴养洁.金(Ⅲ)与杯[4]乙酯合钠(Ⅰ)超分子化合物: [Na(C60H80O12)]+[Au(SCN)4]-的合成、结构及性能[J].无机化学学报,2005,21(3):379-382. |
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