高分散纳米二氧化钛混合晶体的合成、结构与光催化性能
Synthesis, Structure and Photocatalysis of Nano-TiO2 Mixed Crystals
作者单位
王振兴 河北大学化学与环境科学学院保定 071002 
丁士文 河北大学化学与环境科学学院保定 071002 
张美红 河北大学化学与环境科学学院保定 071002 
摘要: 
关键词: 高分散纳米二氧化钛  混晶  制备  光催化性能
基金项目: 
Abstract: Using TiCl4 and urea as the raw materials and nanometric carbon black as plate, nanometric mix-crystals of rutile and anatase TiO2 were prepared at 100 ℃ for 10~180 min by homogeneous precipitation method. The effects of pH on the ratio of nanometer TiO2 mix-crystals were also discussed. TEM measurement indicates that the TiO2 is spherical particles, and the average diameter of the particles is 20 nm. XRD and TG-DTA were also used to characterize the nanometer mix-crystal materials. The photocatalytic experiment show that the mix-crystal material has the best photocatalytic reactivity. After being irradiated under the sunlight for 40 min, the compound can completely degrade the acid-red 3R.
Keywords: nano-TiO2  mix-crystal  preparation  photocatalys
投稿时间:2004-08-23 修订日期:2004-10-19
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王振兴,丁士文,张美红.高分散纳米二氧化钛混合晶体的合成、结构与光催化性能[J].无机化学学报,2005,21(3):437-440.
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