| 双核Cd(Ⅱ)-8-喹啉氧基乙酸根离子配合物的合成与晶体结构 |
| Synthesis and Crystal Structure of Dinuclear Cd(Ⅱ) Complex with 8-quinolinyloxyacetate |
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| 摘要: |
| 关键词: 晶体结构 8-喹啉氧基乙酸 Cd(Ⅱ)配合物 氢键 |
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| Abstract: A novel cadmium(Ⅱ) complex with 8-quinolinyloxyacetate has been prepared and characterized by X-ray diffraction. The complex is a centrosymmetric [Cd2L2Cl4(MeOH)2] dinuclear structure and the Cd(Ⅱ) centre is in a distorted octahedron geometry. The crystal is in triclinic system, space group P1, with a=0.752 2(4) nm, b=1.043 1(5) nm, c=1.097 3(6) nm, α=66.11(2)°, β=72.48(2)°, γ=70.28(2)° and Z=1. The most striking feature of this complex is the formation of a 3D network bridged through the intermolecular N-H…O, O-H…O, C-H…O and C-H…Cl hydrogen bonds and stabilized via intermolecular π-π stacking interactions. CCDC: 224677. |
| Keywords: crystal structure 8-quinolinyloxyacetic acid Cd(Ⅱ) complex hydrogen bonds |
| 投稿时间：2004-08-30 修订日期：2004-11-25 |
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| 王玉红,赵凯元,杜鹃.双核Cd(Ⅱ)-8-喹啉氧基乙酸根离子配合物的合成与晶体结构[J].无机化学学报,2005,21(4):511-514. |
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