| (R)-1，1′-联萘手性单元通过溶胶凝胶法合成杂化硅干凝胶(英) |
| Silica Hybrid Xerogel Incorporating (R)-2,2′-bis(methoxyethoxymethyloxy)-1,1′-binaphthyl Unit via Sol-Gel Process |
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| 摘要: |
| 关键词: (R)-2，2′-联萘酚 有机硅 溶胶凝胶 Heck反应 |
| 基金项目: |
| Abstract: Precursor molecule (R)-6,6′-bis(triethoxysilylethen-2-yl)-2,2′-di(methoxyethoxymethyloxy)-1,1′-binaphthyl (R-2) was synthesized by Pd-catalyzed Heck reaction of (R)-6,6′-dibromo-2,2′-di(methoxyethoxymethyloxy)-1,1′-binaphthyl (R-1) intermediate with vinyltriethoxysilane. The hydrolysis and polycondensation of the precursor R-2 produced the corresponding xerogel. Both precursor and xerogel were analysed by NMR, FTIR, UV, CD spectra, fluorescent spectroscopy, polarimetry and elemental analysis. The precursor and xerogel can emit strong blue fluorescence and are expected to have a potential application in the separation of chiral molecules as fluorescent sensor. The precursor exhibits strong Cotton effect in its circular dichroism (CD) spectrum indicating a highly rigid structure. |
| Keywords: (R)-2,2′-BINOL , organic silicon sol-gel Heck reaction |
| 投稿时间：2004-09-06 修订日期：2004-12-10 |
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| 成义祥,宋金峰,陈令武,邹小伟.(R)-1，1′-联萘手性单元通过溶胶凝胶法合成杂化硅干凝胶(英)[J].无机化学学报,2005,21(4):561-564. |
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