| 对甲苯磺酰谷氨酸桥联的一维双链锰配合物的合成、表征与晶体结构 |
| Synthesis, Characterization and Crystal Structure of a 1D Double-chain Manganese Complex Bridged by N-p-tolysulfonyl-L-glutamic Acid |
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| 摘要: |
| 关键词: 对甲苯磺酰谷氨酸 锰配合物 晶体结构 |
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| Abstract: A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P212121. The crystal data are: a=0.530 78(17) nm, b=1.723 9(5) nm, c=2.456 9(8) nm, Z=4, μ=0.729 mm-1, Dc=1.579 g·cm-3, V=2.248 1(12) nm3, R1=0.033 1, ωR2=0.078 9. In the title complex, each Mn(Ⅱ) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo2- ligands. The γ-carboxyl coordinates to Mn(Ⅱ) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode. CCDC: 253910. |
| Keywords: N-p-tolysulfonyl-L-glutamic acid manganese complex crystal structure |
| 投稿时间：2004-07-05 修订日期：2004-12-23 |
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| 陈满生,梁福沛,胡瑞祥,马运声,宋丽华.对甲苯磺酰谷氨酸桥联的一维双链锰配合物的合成、表征与晶体结构[J].无机化学学报,2005,21(5):689-692. |
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