| 一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英) |
| Synthesis, Crystal Structure and Properties of a New Thiadiazolen Two-dimensional Polymer of H2ADTZ with Mn(Ⅱ) |
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| 摘要: |
| 关键词: 锰 聚合物 噻二唑衍生物 氢键 循环伏安 |
| 基金项目: |
| Abstract: A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H2ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H2O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532. |
| Keywords: Mn(Ⅱ) polymer thiadiazole-derivative hydrogen bonds cyclic voltammetry |
| 投稿时间：2004-08-22 修订日期：2004-12-02 |
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| 娄新华,朱玉,高辉,朱爱新,樊耀亭,侯红卫,卢会杰.一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英)[J].无机化学学报,2005,21(5):716-720. |
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