锂离子电池正极材料LiNi1-xCoxO2的合成及电化学性能研究
Synthesis and Electrochemical Performance of LiNi1-xCoxO2 Cathode Materials for Lithium Ion Batteries
作者单位
黄元乔 武汉大学化学与分子科学学院武汉 430072
湖北教育学院化学系武汉 430205 
郭文勇 武汉大学化学与分子科学学院武汉 430072 
李道聪 武汉大学化学与分子科学学院武汉 430072 
彭正合 武汉大学化学与分子科学学院武汉 430072 
周运鸿 武汉大学化学与分子科学学院武汉 430072 
摘要: 
关键词: 锂镍钴氧化物  锂离子电池  正电极材料  充放电比容量
基金项目: 
Abstract: LiNi1-xCoxO2 cathode materials for lithium ion batteries were synthesized by the co-precipitation and solid-state reaction methods with LiOH·H2O, Ni(NO3)2·6H2O and Co(NO3)2·6H2O as raw materials. The materials were characterized by XRD, SEM and electrochemical tests. The results showed that synthesized cathode materials were with layered structure similar to α-NaFeO2 and uniform morphology and nearly normal grain size distribution and better electrochemical performance when x was 0.18. The first charge and discharge capacity of the cathode material was 224.3 mAh·g-1 and 194.2 mAh·g-1, respectively. 88.5% of the first discharge capacity remained at the 20th cycle.
Keywords: lithium-cobalt-nickel oxide  lithium ion battery cathode material  charge and discharge capacity
投稿时间:2004-09-20 修订日期:2004-12-06
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黄元乔,郭文勇,李道聪,彭正合,周运鸿.锂离子电池正极材料LiNi1-xCoxO2的合成及电化学性能研究[J].无机化学学报,2005,21(5):736-740.
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