γ辐照诱导金纳米粒子的形成和形貌重塑
Gold Nanorods: γ-Ray Induced Formation and Morphology Reshaping
作者单位
范欣 南京大学配位化学国家重点实验室南京 210093 
尹桂 南京大学配位化学国家重点实验室南京 210093 
徐正 南京大学配位化学国家重点实验室南京 210093 
摘要: 在十六烷基三甲基溴化铵(CTAB)水溶液中,抗坏血酸(AA)将橙黄色的Au3+还原为无色的Au+,在γ射线产生的水合电子的作用下,Au+进一步还被原成Au0,并在微量的Ag+诱导所产生的CTAB胶束中生长成为Au纳米棒。控制γ辐照的时间,可以实现金纳米粒子的形貌重塑,即由最初的棒状变为立方体,最终变为多面体。
关键词: γ辐照  形貌变化  金纳米粒子
基金项目: 
Abstract: The Au3+ ions are reduced to Au+ ion with the color change from orange to colorless by ascorbic acid (AA) in aqueous solution of CTAB (cetyltrimethylammonium bromide). With the effect of γ-irradiation, the Au+ ions can be further reduced to Au0, and then form low aspect ratio gold nanorods in the rod-like CTAB micelles induced by a trace amount of Ag+. The reshaping of gold nanoparticles from initial rods to cube and finally to polyhedron can also be achieved by controlling the irradiation time.
Keywords: γ-irradiation  morphology change  gold nanoparticles
投稿时间:2005-04-18 修订日期:2005-05-09
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范欣,尹桂,徐正.γ辐照诱导金纳米粒子的形成和形貌重塑[J].无机化学学报,2005,21(6):822-825.
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