正辛烷为稀释剂不对称N-甲基-N-辛基烷基酰胺萃取铀(Ⅵ)的研究(英)
Extraction of U(Ⅵ) with Unsymmetrical N-methyl-N-octyl alkylamide in n-Octane
作者单位
张振伟 济南大学化学化工学院济南 250022 
崔玉 济南大学化学化工学院济南 250022
山东大学化学化工学院济南 250100 
孙国新 济南大学化学化工学院济南 250022 
孙思修 山东大学化学化工学院济南 250100 
摘要: 
关键词: N-甲基-N-辛基烷基酰胺  正辛烷  萃取  硝酸铀酰
基金项目: 
Abstract: The extraction of uranyl nitrate was studied with newly synthesized unsymmetrical alkylamides, N-methyl-N-octyloctylamide (MOOA), N-methyl-N-octyldecanamide (MODA), and N-methyl-N-octyldodecanamide (MODOA), employing n-octane as diluent. The effect of the concentrations of nitric acid, sodium nitrate and extractants on the extraction was investigated and the extraction mechanism was suggested. The effect of temperature on the extraction was also studied and the related thermodynamic functions were calculated. The extracted species were characterized by FTIR spectrometry.
Keywords: N-methyl-N-octyl alkylamide  n-octane  extraction  uranyl nitrate
投稿时间:2004-10-08 修订日期:2004-12-04
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张振伟,崔玉,孙国新,孙思修.正辛烷为稀释剂不对称N-甲基-N-辛基烷基酰胺萃取铀(Ⅵ)的研究(英)[J].无机化学学报,2005,21(6):885-888.
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