| 新型一维链状化合物N-(m-二茂铁苯基)甲酰胺的合成及晶体结构(英) | |
| Synthesis and Crystal Structure of a Novel One-Dimensional N-(m-Ferrocenylphenyl)-Formamide | |
| 摘要: | |
| 关键词: 二茂铁 晶体结构 氢键 循环伏安 | |
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| Abstract: N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in the monoclinic, P21/c space group, with a=0.140 94(3) nm, b=0.102 87(2) nm, c=0.100 26(2) nm, β=104.85(3)° and final R indices [I>2σ(I)] R1=0.072 7, wR2=0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H…O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511. | |
| Keywords: ferrocene crystal structure hydrogen bond cyclic voltammetry | |
| 投稿时间：2004-11-23 修订日期：2005-02-24 | |
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| 徐琰,付勇,冉春玲,王非,冶保献,宋毛平.新型一维链状化合物N-(m-二茂铁苯基)甲酰胺的合成及晶体结构(英)[J].无机化学学报,2005,21(7):1045-1048. | |
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