| 苯基乙酰甲基亚砜与碱土金属配合物的合成和晶体结构(英) |
| Synthesis and Crystal Structure of Phenyl-acetyl Methylene Sulfoxide Complexes with Alkaline-Earth Metal |
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| 摘要: 本文选取苯基乙酰甲基亚砜(C6H5SOCH2COCH3)作为配体与碱土金属(钙、锶)的高氯酸盐反应得到配合物的单晶，对它们进行了元素分析及红外光谱表征，它们的化学式为[ML6](ClO4)2(M=Ca、Sr；L=C6H5SOCH2COCH3)。并用X-ray单晶衍射法测定了钙、锶配合物的晶体结构。 |
| 关键词: 碱土金属 X-ray晶体结构 苯基乙酰甲基亚砜 |
| 基金项目: |
| Abstract: Two complexes of alkaline-earth metals perchlorate with phenyl-acetylmethylene sulfoxide(C6H5SOCH2COCH3) have been synthesized and characterized by elemental analysis and IR spectra. Composition of complexes are [ML6](ClO4)2(M=Ca, Sr; L=C6H5SOCH2COCH3). The crystal structures of the complexes of Ca and Sr were determined by X-ray single crystal diffraction analysis. CCDC: 23880 (Ca); 23881 (Sr). |
| Keywords: alkaline-earth metals X-ray crystal structure phenyl-acetylmethylene sulfoxide |
| 投稿时间：2004-12-02 修订日期：2005-06-02 |
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| 李文先,王宏胜,胡瑞珏,其其格.苯基乙酰甲基亚砜与碱土金属配合物的合成和晶体结构(英)[J].无机化学学报,2005,21(9):1291-1295. |
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