| 自旋交叉配合物[Fe(mtt)(phen)(NCS)2]·py的合成和磁性研究 |
| The Synthesis and Magnetic Study of Spin Crossover Complex [Fe(mtt)(phen)(NCS)2]·py |
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| 摘要: 设计制备了一个新的自旋交叉配合物[Fe(mtt)(phen)(NCS)2]·py。通过元素分析、红外光谱、质谱和紫外光谱等方法对该配合物进行结构表征。变温磁化率研究发现该配合物的自旋转换温度为Tc↑=197 K, Tc↓=188 K，回滞宽度9 K。通过与同体系其他配合物的比较发现，配体的修饰对自旋交叉临界温度以及回滞宽度都有显著影响。 |
| 关键词: 配体 磁化率 自旋交叉 自旋转换 分子材料 |
| 基金项目: |
| Abstract: A new spin crossover [Fe(mtt)(phen)(NCS)2]·py was prepared. Elemental analysis, infrared spectrum, electrospray ionization mass spectroscopy and ultraviolet spectroscopy were used to study the structure of the complex. The temperature dependence of magnetic susceptibility shows that the temperatures of spin transition are Tc↑= 197 K and Tc↓= 188 K, respectively, and the hysteresis loop is 9 K. By comparing the complex with the other resemble structural complexes, it reveals that the modification of ligand will influence greatly on the critical temperature and hysteresis loop of spin crossover. |
| Keywords: ligand magnetic susceptibilities spin crossover spin transition molecule materia |
| 投稿时间：2005-03-06 修订日期：2005-05-09 |
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| 陶建清,顾志国,王天维,左景林.自旋交叉配合物[Fe(mtt)(phen)(NCS)2]·py的合成和磁性研究[J].无机化学学报,2005,21(10):1471-1474. |
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