| 一种具有一维链状结构的4f-3d双核配合物[Eu(DMSO)3(H2O)3Cr(CN)6]·H2O(DMSO=二甲亚砜)的合成、晶体结构和磁性研究(英) |
| Synthesis, Crystal Structure, Magnetic Properties of a Bimetallic 4f-3d Array [Eu(DMSO)3(H2O)3Cr(CN)6]·H2O(DMSO=Dimethylsulfoxide) with One-Dimensional Chain Molecular Structure |
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| 摘要: |
| 关键词: 4f-3d配合物 氰桥配合物 磁性能 |
| 基金项目: |
| Abstract: A new cyano-bridged complex [Eu(DMSO)3(H2O)3Cr(CN)6]·H2O with one-dimensional chain molecular structure was synthesized and characterized. The crystal data for the title complex: orthorhombic, P212121, a=0.972 2(3) nm, b=1.489 5(4) nm, c=1.748 6(5)nm, Z=4, μ=3.171 mm-1, final R1=0.020 4, wR2=0.043 4. From magnetic susceptibility measurements the complex was found to exhibit a weak ferromagnetic interaction between the Eu (Ⅲ)and Cr(Ⅲ)atoms. CCDC: 272212. |
| Keywords: 4f-3d complex cyano-bridged complex magnetic properties |
| 投稿时间：2005-02-22 修订日期：2005-04-28 |
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| 梁淑惠,车云霞,郑吉民.一种具有一维链状结构的4f-3d双核配合物[Eu(DMSO)3(H2O)3Cr(CN)6]·H2O(DMSO=二甲亚砜)的合成、晶体结构和磁性研究(英)[J].无机化学学报,2005,21(10):1520-1524. |
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