1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构
Synthesis and Crystal Structure of a Novel Self-assembled (1,4-discyclohexyl cucurbituril) Sodium(Ⅰ) Complex
作者单位
郑利梅 贵州大学应用化学研究所贵阳 550025 
祝黔江 贵州大学应用化学研究所贵阳 550025 
朱建男 贵州大学应用化学研究所贵阳 550025 
张云黔 贵州大学应用化学研究所贵阳 550025 
陶朱 贵州大学应用化学研究所贵阳 550025 
薛赛凤 贵州大学应用化学研究所贵阳 550025 
魏赞斌 厦门大学化学系厦门 361005 
龙腊生 厦门大学化学系厦门 361005 
摘要: 
关键词: 1,4-二环己基取代六元瓜环  晶体结构  自组装实体
基金项目: 
Abstract: A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ[6]) with sodium(Ⅰ) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ[6] included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ[6] with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400.
Keywords: 1,4-dicyclohexyl cucurbituril  crystal structure  self-assembled entity
投稿时间:2004-10-25 修订日期:2005-08-04
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郑利梅,祝黔江,朱建男,张云黔,陶朱,薛赛凤,魏赞斌,龙腊生.1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构[J].无机化学学报,2005,21(10):1583-1588.
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