| 一维链状配位聚合物[Ag(bix)(NO3)(H2O)]n的合成和晶体结构 | |
| Synthesis and Crystal Structure of One-Dimensional Chainlike Coordination Polymer [Ag(bix)(NO3)(H2O)]n | |
| 摘要: | |
| 关键词: 银(Ⅰ)配合物 晶体结构 配位聚合物 | |
| 基金项目: | |
| Abstract: A one-dimensional (1D) Z conformation coordination polymer, [Ag(bix)(NO3)(H2O)]n was obtained by the reaction between AgNO3 and flexible ligand of 1,4-bis(imidazol-1-ylmethyl)-benzene under hydrothermal conditions. It crystallizes in triclinic with space group P1. The crystallographic data of the compound are: a=0.777 1(2) nm, b=1.043 4(3) nm, c=1.082 7(3) nm, α=71.403(4)°, β=80.946(5)°, γ=88.794(4)°. The 1D chainlike structure was connected by π-π interaction between phenyl rings, leading to a 2D layered network. The lattice water and the NO3- anions were involved between the layers, therefore the 2D layered structure further extended to an intricate 3D framework. CCDC: 257100. | |
| Keywords: silver(Ⅰ) complex crystal structure coordination polymer | |
| 投稿时间：2005-04-05 修订日期：2005-09-01 | |
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| 吴燕萍,温丽丽,李一志,党东宾,鲁振达,孟庆金.一维链状配位聚合物[Ag(bix)(NO3)(H2O)]n的合成和晶体结构[J].无机化学学报,2005,21(11):1759-1762. | |
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