| Abstract: The title complex has been synthesized by using terephthalic acid (PTA), 1,10-phenanthroline (phen) and copper monohydrate. It crystallizes in monoclinic space group C2/c with a=2.959 0(2) nm, b=1.466 4(10) nm, c=1.764 3(12) nm, β=105.593(11)°, V=7.372(9)
nm3, Dc=1.489 g·cm-3, Z=8, F(000)=3 416, R1=0.043 6,
wR2= 0.151 9. The crystal structure shows that the copper atom is coordinated with four nitrogen atoms from two phens and one oxygen atom from one terephthalic acid, forming a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 277047. |
| 李薇,李昶红,杨颖群,邝代治,陈志敏,徐伟箭,陈满生.配合物[Cu(PTA)(phen)2]·(PTA)·(H2O)4的合成、晶体结构及电化学性质[J].无机化学学报,2006,22(1):101-105. |
