| Abstract: The title complex Cu(L)2 [HL=N-(5-bromosalicylidene)-2-aminoethanol] was synthesized by the reaction of
Cu(CH3COO)2·H2O with N-(5-bromosalicylidene)-2-aminoethanol in the ethanol. It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The crystal of the title complex
[Cu(C9H9BrNO2)2] belongs to monoclinic, space group
P21/n with a=1.319 1(5) nm, b=0.444 58(16) nm, c=1.656 7(6) nm, β=91.226(5)°, V=0.971 46(6)
nm3, Z=2, Dc=1.879 Mg·m-3, μ=5.264 mm-1, F(000)=542, and final
R1=0.045 6, wR2=0.097 0. The complex comprises a four-coordinated copper(II) center, with an
N2O2 planar coordination environment. The molecules are connected by hydrogen bonds to form two-dimensional layered structure. CCDC: 274180. |
