溶液中Fe(VI)向Fe(IV)转化反应的分光光度法跟踪
Conversion Reaction of Fe(VI) to Fe(IV) in Solution Traced by Visible Spectrometry
作者单位
贾汉东 郑州大学化学系, 郑州 450052 
鲍改玲 郑州大学化学系, 郑州 450052 
于伟伟 郑州大学化学系, 郑州 450052 
摘要: 
关键词: 高铁(VI)酸盐  高铁(IV)酸盐  转化反应  分光光度法
基金项目: 
Abstract: Different concentrations of ferrate(VI) with ClO- and without ClO- in alkaline solution were traced by visible spectrometry, and the conversion reaction of Fe(VI) to Fe(IV) was found to exist, in condition that c was ≥ 6 mol·L-1. ClO- would slow down the decomposition reaction rate of Ferrate(VI) and increase the product concentration of Fe(IV) in the system.
Keywords: ferrate(VI), ferrate(IV), conversion reaction, spectrophotometry
 
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贾汉东,鲍改玲,于伟伟.溶液中Fe(VI)向Fe(IV)转化反应的分光光度法跟踪[J].无机化学学报,2006,22(1):124-128.
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