| 边界条件下铁镍纳米合金与一碳氯化物反应性能的研究 |
| Reaction Characteristics of Fe-Ni Nano-alloy and CCl4, CHCl3, CH2Cl2 under Boundary Condition |
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| 摘要: |
| 关键词: 铁镍纳米合金 一碳氯化物 |
| 基金项目: |
| Abstract: Fe-Ni nano-alloy was prepared by chemical reduction with KBH4 as reducing agent and PEG as dispersant.The reacting performance of Fe-Ni nano-alloy with CCl4, CHCl3, CH2Cl2 has been studied. The high superficial energy of nano-alloy causes breakage of C-Cl bond in the presence of a little oxygen. XRD result shows the main phases of the alloy embedded with elemental carbon are Fe3C, Fe2C. The result of element analysis indicates that the reaction products are mainly FeCl2, NiCl2, Cl2. |
| Keywords: Fe-Ni nano-alloy carbon chloride |
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| 董国君,张杰,万幸,张密林.边界条件下铁镍纳米合金与一碳氯化物反应性能的研究[J].无机化学学报,2006,22(1):175-178. |
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