自激活白光发射Ba2TiP2O9发光材料的发光特性
Luminescent Properties of the Self-activated White-light Emitting Phosphor Ba2TiP2O9
作者单位
刘春波 吉林师范大学化学学院四平 136000 
车广波 吉林师范大学化学学院四平 136000 
摘要: 
关键词: 发光材料  磷酸盐  钛离子  白光  余辉
基金项目: 
Abstract: The Ba2TiP2O9 phosphor was synthesized via the conventional high-temperature solid-state method. The Ba2TiP2O9 phosphor showed high luminance white-light emitting when excited under 254 nm radiation. Furthermore, obvious long-lasting phosphorescence could be observed when the UV excitation source had been removed. XRD and photoluminescence (PL) spectra as well as the luminance decay were used to characterize the synthesized phosphor. The results of XRD indicated that the products obtained under 1 100 ℃ for 3 h had a good crystallization. Both the PL spectra and luminance decay measurement revealed that this kind of phosphors was a new kind of white-light-emitting phosphor. The thermoluminescence properties have also been investigated. The energy level of the 352 K and 493 K TL peaks have also been calculated and found that their energy level values were 0.35 eV and 1.08 eV, respectively. The 352 K TL peak is responsible for the origin of the long-lasting phosphorescence.
Keywords: phosphor  phosphate  titanium ions  white-light-emitting  afterglow
 
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刘春波,车广波.自激活白光发射Ba2TiP2O9发光材料的发光特性[J].无机化学学报,2006,22(3):503-506.
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