室温电化学沉积Ba1-xCaxMoO4多晶固溶体薄膜
Electrochemical Deposition of Ba1-xCaxMoO4 Polycrystalline Solid-solution Thin Film at Room Temperature
作者单位
毕剑 四川大学材料科学与工程学院成都 610064
四川师范大学化学与材料科学学院成都 610066 
余萍 四川大学材料科学与工程学院成都 610064 
陈连平 四川大学材料科学与工程学院成都 610064 
金晓玲 四川大学材料科学与工程学院成都 610064 
赖欣 四川师范大学化学与材料科学学院成都 610066 
肖定全 四川大学材料科学与工程学院成都 610064 
摘要: 
关键词: Ba1-xCaxMoO4薄膜  固溶体  电化学沉积
基金项目: 
Abstract: At room temperature, Ba1-xCaxMoO4 polycrystalline solid solution thin films were prepared directly in contained Ca2+ and Ba2+ alkaline solution by electrochemical anode oxidation method. The crystal phase structure, surface morphology, ratio of compositions and room temperature fluorescence properties of the as-grown films were measured by using XRD, SEM, EDAX and Fluorescence Analysis techniques, respectively. The results reveal that the ratio of composition of Ba1-xCaxMoO4 films can be modulated by controlling the ratio of Ca2+ and Ba2+ in starting solutions; moreover it has important influence of ratio of composition of the films on the grain growth, the crystal lattice constant, the surface morphology as well as the fluorescence properties of the as-grown films.
Keywords: Ba1-xCaxMoO4 thin films  solid solution  electrochemical deposition
 
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毕剑,余萍,陈连平,金晓玲,赖欣,肖定全.室温电化学沉积Ba1-xCaxMoO4多晶固溶体薄膜[J].无机化学学报,2006,22(5):909-912.
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