| 三种马来二腈基二硫烯镍(Ⅲ)离子对配合物的制备和结构表征 |
| Syntheses and Crystal Structures of Three Ionic Pair Complexes Based on [Ni(mnt)2]- Ions |
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| 摘要: 合成了3种离子对配合物 [1-benzyl-3-bromopyridium]+[Ni(mnt)2]- (1)，[1-(4′-flurobenzyl)-3-bromopyridiunm]+[Ni(mnt)2]- (2)，[1-(4′-cholorobenzyl)-3-bromopyridium]+[Ni(mnt)2]- (3)，(mnt=马来二腈基二硫烯，maleonitrile dithiolate)获得了单晶并解析了它们的单晶结构。 |
| 关键词: 马来二腈基二硫烯(mnt) Ni(Ⅲ)配合物 晶体结构 |
| 基金项目: |
| Abstract: We report the syntheses and crystal structures of 3 ionic pair coordination compounds which consist of [Ni(Ⅲ)(mnt)2]- anion and bended [1-(4′-Rbenzyl)-3-bromopyridinium]+ cation, (mnt=maleonitrile dithiolate, R=H, F and Cl). CCDC: 609512, 1; 609513, 2; 609511, 3. |
| Keywords: maleonitrile dithiolate (mnt) Ni(Ⅲ) coordination compounds crystal structure |
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| 李昊,李一志,倪兆平,孟庆金.三种马来二腈基二硫烯镍(Ⅲ)离子对配合物的制备和结构表征[J].无机化学学报,2006,22(7):1231-1234. |
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