| 两个由1,1′-环己烷二乙酸构筑的镉的配合物的合成、晶体结构和荧光性质(英文) | |
| Syntheses, Structures and Fluorescence of Two Cd(Ⅱ) Complexes Constructed from 1,1′-Cyclohexanediacetic Acid | |
| 摘要: 通过邻羧苯乙酸、1,10-邻菲啰啉及硝酸镉的溶剂热反应合成了2个配合物：[Cd(phen)(chdc)]n (1)和[Cd(phen)(chdc)(H2O)]n (2)。X-射线单晶衍射显示：1是梯状双链结构；2是单链结构，单链再通过氢键连接成双链。虽然1和2的组分相似，但它们在固态条件下的荧光发射却大不一样，可能在光化学方面有潜在的应用。 | |
| 关键词: 柔性配体 镉配合物 1，1′-环己烷二乙酸 溶剂热合成 荧光 | |
| 基金项目: | |
| Abstract: Two complexes of 1,1′-cyclohexanediacetic acid (H2chdc), [Cd(phen)(chdc)]n (1) and [Cd(phen)(chdc)(H2O)]n (2), have been synthesized through solvothermal reactions of H2chdcc, 1,10-phenanthroline (phen) and cadmium nitrate. The crystal structures of two complexes reveal that 1 has a ladder-like double-chain structure, while 2 consists of linear single chains, which are further linked to form double-chains through hydrogen bonding. Although consisted of similar components, 1 and 2 exhibit different intense fluorescence emission in solid state, which may have promising application in photophysical chemistry. CCDC: 285079, 1; 285080, 2. | |
| Keywords: flexible ligand Cd(Ⅱ) complex 1,1′-cyclohexanediacetic acid solvothermal synthesis fluorescence | |
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| 何锦润,王玉玲,毕文华,曹荣.两个由1,1′-环己烷二乙酸构筑的镉的配合物的合成、晶体结构和荧光性质(英文)[J].无机化学学报,2006,22(8):1380-1386. | |
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