无机化学学报

双(3-对甲苯基-2-硫代咪唑-1-基)-(3-甲基-5-苯基吡唑-1-基)硼氢酸根的镉及钴配合物的合成与结构表征(英文)

Syntheses and Crystal Structures of Cadmium(Ⅱ) and Cobalt(Ⅱ) Complexes with Hydro[bis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)] Borate

作者	单位
舒谋海	上海交通大学化学化工学院，上海 200240
屠春来	上海交通大学化学化工学院，上海 200240
崔靖	上海交通大学化学化工学院，上海 200240
孙杰	中国科学院上海有机化学研究所，上海 200032

摘要:

关键词: 三角架配体镉钴晶体结构

基金项目:

Abstract: Two new complexes CdL₂ (1) and CoL₂ (2) were synthesized by reactions of L {L =hydro[bis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)]borate} with cadmium(Ⅱ) and cobalt(Ⅱ) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S₄H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.

Keywords: tripodal ligand cadmium cobalt crystal structure

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舒谋海,屠春来,崔靖,孙杰.双(3-对甲苯基-2-硫代咪唑-1-基)-(3-甲基-5-苯基吡唑-1-基)硼氢酸根的镉及钴配合物的合成与结构表征(英文)[J].无机化学学报,2006,22(8):1507-1510.

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