| 由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O(英文) | |
| One-dimensional Chain Polyoxotungstate Decorated with Amino Acid Copper Complex: (H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O | |
| 摘要: | |
| 关键词: 有机无机杂化材料 水热合成 晶体结构 钨多酸 氨基酸 | |
| 基金项目: | |
| Abstract: A new compound, (H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O(1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid ligand. Two cis-{Cu(Gly)2}2+ engraft into the (H2W12O42)10- with Cu-O bond of 0.241 2(7) nm, and Na+ ions linked these [(Cu(Gly)2)2(H2W12O42)]6- clusters into a one-dimensional chain. CCDC: 278000. | |
| Keywords: organic-inorganic hybrid hydrothermal synthesis crystal structure polyoxotungstate amino acid | |
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| 吴小园,张全争,何翔,陈淑妹,杨文斌,卢灿忠.由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O(英文)[J].无机化学学报,2006,22(8):1511-1516. | |
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