Abstract: The hydrothermal treatment of 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (CDTO) with Cu(OAc)2·4H2O in the presence of methanol as solvent offers a molecular coordination compound [Cu(CDTO)2(OAc)2] (1), whose dielectric physical properties has been investigated. Crystal data for 1: Triclinic, P1, a=0.859 06(10) nm, b=1.053 11(13) nm, c=1.202 96(14) nm. α=111.540(2)°, β=108.899(2)°, γ=196.249(3)°. V=0.925 09(19) nm3, Z=1, 3 579 unique data (θmax=25.99°), R=0.053 9 (2 888 [I≥2σ(I)] reflections), wR=0.154 1 (all data), ρmax=0.55 e·nm-3. CCDC: 605591. |