掺杂钒和硅对TiO2薄膜超亲水性的影响
Effect of Vanadium and Sillicon Dopant on Super-hydrophilicity of TiO2 Thin Films
作者单位
蒋新 浙江大学材料与化工学院, 杭州 310027 
吴艳香 浙江大学材料与化工学院, 杭州 310027 
陈喜明 浙江大学材料与化工学院, 杭州 310027 
摘要: 
关键词: TiO2  复合薄膜  接触角  超亲水
基金项目: 
Abstract: V2O5-TiO2, SiO2-TiO2 , SiO2-V2O5-TiO2 composite nanometer thin film and TiO2 single thin film on glass substrates were prepared by sol-gel method and dip-coating technique, respectively. The films were characterized by X-ray diffraction (XRD), high-resolution scanning electron microscopy (HRSEM). The hydrophilicity of the films was determined by water contact angles on the films. The results show that the addition of V2O5 to TiO2 thin films could keep good hydrophilicity under sunlight on the TiO2 thin films and make surface morphology of thin films dense and crystalline size decrease. The addition of SiO2 could suppress crystal growth of TiO2 crystal and improve super-hydrophilicity of TiO2 thin films. The contact angle in SiO2-V2O5-TiO2 thin composite films declined with the increase in V2O5 content, declined firstly and then increased with SiO2 content. The dopant of V2O5 on TiO2 thin films could produce a visible-light response to the films, but the addition of SiO2 could not do much help in improving the hydrophilicity.
Keywords: TiO2  thin composite films  contact angle  super-hydrophilicity
 
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蒋新,吴艳香,陈喜明.掺杂钒和硅对TiO2薄膜超亲水性的影响[J].无机化学学报,2006,22(9):1723-1727.
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