| Abstract: Two novel 3D coordination ploymers [Mn2(Pyzca)2Cl2]n (1) and [Mn2(Pyzca)2Br2]n (2) were synthesized by the hydrothermal reaction. The structures were characterized by elemental analysis, IR and single crystal X-ray diffraction. Crystallographic data of the title coordination polymers 1 and 2: 1: C10H6N4O4Cl2Mn2, Triclinic, P1, a=0.616 4(17) nm, b=0.768 6(2) nm, c=1.394 6(4) nm, α=78.476(5)°, β=81.407(5)°, γ=77.943(5)°, Z=2, V=0.629 1(3) nm3; 2: C10H6N4O4Br2Mn2, Triclinic, P1, a=0.623 6(17) nm, b=0.774 0(2) nm, c=1.411 7(4) nm, α=77.720(5)°, β=81.673(5)°, γ=79.000(5)°, Z=2, V=0.649 6(3) nm3. The coordination polymers have both a three-dimensional structure networks. CCDC: 604729, 1; 604730, 2. |
