| {[Cu4(nip)4(4，4′-bipy)4(DMF)4]·CH3OH}n配合物的合成与晶体结构 |
| Synthesis and Crystal Structure of {[Cu4(nip)4(4，4′-bipy)4(DMF)4]·CH3OH}n |
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| 摘要: |
| 关键词: 5-硝基间苯二甲酸 二维网络结构 配位聚合物 |
| 基金项目: |
| Abstract: A coordination polymer, {[Cu4(nip)4(4，4′-bipy)4(DMF)4]·CH3OH}n, have been synthesized by the layer method using 5-nitroisophthalic acid (H2nip), Cu(CH3COOH)2 and 4,4′-bipyridine(4,4′-bipy) with three solutions in a marrow tube and structurally characterized by X-ray single-crystal structure analysis. The results indicated that the nip ligand has a μ2 mono-atomic bridging-monodentate coordination mode and the structure is a two-dimensional network. CCDC: 623420. |
| Keywords: 5-nitroisophthalic acid 2D network structure coordination polymer |
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| 周以力,何洪银,陈洁.{[Cu4(nip)4(4，4′-bipy)4(DMF)4]·CH3OH}n配合物的合成与晶体结构[J].无机化学学报,2006,22(12):2239-2241. |
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