多重射流燃烧反应制备的TiO2/ SiO2纳米复合颗粒的形态和结构 |
Morphology and Structure of TiO2/ SiO2 Nanocomposites Prepared by Muti-jet Flame Reactor |
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摘要: |
关键词: 多重射流火焰 纳米复合 二氧化钛 二氧化硅 |
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Abstract: TiO2-SiO2 nanocomposite particles were prepared in premixed H2 / Air flame, and the morphology and structure of these nanocomposites were characterized by FTIR, XRD, TEM and HRTEM. The morphology of SiO2 / TiO2 nanocomposites was different from that of pure TiO2 or SiO2 nanoparticles, and the chemical bond of Ti-O-Si was found in the nanocomposites indicating that the TiO2 / SiO2 nanocomposites were not merely a physical mixture of TiO2 and SiO2. TiO2 nanocrystalline grains with sizes of 1~2 nm were homogeneously dispersed in the amorphous SiO2 matrix when TiCl4 and SiCl4 were mixed at molecular level in the flame. The particle size and rutile content decreased with increasing of SiO2 molar ratio. |
Keywords: muti-jet flame nanocomposite titanium dioxide silicon dioxide |
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胡彦杰,李春忠,顾锋,姜海波,赵尹.多重射流燃烧反应制备的TiO2/ SiO2纳米复合颗粒的形态和结构[J].无机化学学报,2006,22(12):2253-2257. |
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