磷酸铵与多聚磷酸铵插层可膨胀石墨的制备
Preparation of Expandable Graphite Intercalated by Ammonium Phosphate and Ammonium Polyphosphate
作者单位
韩志东 哈尔滨理工大学材料科学与工程学院哈尔滨 150040 
张达威 哈尔滨理工大学材料科学与工程学院哈尔滨 150040 
董丽敏 哈尔滨理工大学材料科学与工程学院哈尔滨 150040 
张显友 哈尔滨理工大学材料科学与工程学院哈尔滨 150040 
摘要: 
关键词: 石墨  可膨胀石墨  磷酸铵  多聚磷酸铵
基金项目: 
Abstract: Expandable graphite intercalated by ammonium phosphate (AP) or ammonium polyphosphate (APP) was prepared by direct intercalation and two-step method, respectively. The products from two-step method show higher expansion volume, more weight increase and more weight loss after expansion, suggesting that the two-step method is a favorable method for preparation of APP intercalated EG. XRD provides convincing evidence for successful formation of APP-EG by showing strong diffraction peak at much lower 2θ angle. Scanning electron microscopy (SEM) with energy dispersive X-ray Spectroscopy (EDS) gives more evidence for intercalation of APP in the graphite layers.
Keywords: graphite  expandable graphite  ammonium phosphate  ammonium polyphosphate
 
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韩志东,张达威,董丽敏,张显友.磷酸铵与多聚磷酸铵插层可膨胀石墨的制备[J].无机化学学报,2007,23(2):286-290.
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