不同温度下选择性合成硫氰酸亚铜与硫化亚铜微晶(英文)
Selective Synthesis of CuSCN and Cu2S Crystallites at Different Reaction Temperatures
作者单位
安长华 中国石油大学(华东)化学化工学院东营 257061 
陈祥迎 合肥工业大学化工学院合肥 230009 
王淑涛 中国石油大学(华东)化学化工学院东营 257061 
摘要: 
关键词: 硫属化合物  选择性合成  微晶
基金项目: 
Abstract: Hexagonal CuSCN and cubic Cu2S micro-scale crystallites have been selectively fabricated using CuCl2·2H2O and KSCN as the starting materials at 30 ℃ and 220 ℃, respectively. The results reveal that the reaction temperature plays a key role in obtaining pure phase of CuSCN and Cu2S crystallites. Nearly monodispersed Cu2S nanocrystals were prepared by introducing surfactant into reaction system. The possible reaction mechanism is also discussed.
Keywords: chalcogenides  selective synthesis  micro-crystallite
 
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安长华,陈祥迎,王淑涛.不同温度下选择性合成硫氰酸亚铜与硫化亚铜微晶(英文)[J].无机化学学报,2007,23(2):319-322.
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