氯化钠对锂离子电池石墨负极的修饰改性(英文)
Modification of Graphite Anode for Li-ion Batteries by Sodium Chloride
作者单位
周友元 中南大学冶金科学与工程学院长沙 410083 
李新海 中南大学冶金科学与工程学院长沙 410083 
郭华军 中南大学冶金科学与工程学院长沙 410083 
王志兴 中南大学冶金科学与工程学院长沙 410083 
杨勇 中南大学冶金科学与工程学院长沙 410083 
朱文明 中南大学冶金科学与工程学院长沙 410083 
摘要: 
关键词: 锂离子电池  石墨  氯化钠  负极
基金项目: 
Abstract: The electrochemical performance of a graphite electrode for rechargeable lithium-ion batteries was improved by pretreatment of graphite powders with NaCl aqueous solutions. The procedure of the pretreatment was simple and easy. Graphite powders were dispersed in the aqueous solutions of sodium chloride, followed by stirring, heating and drying. The irreversible capacity at the initial cycle was suppressed by the modification. The sample modified with 1% NaCl had the best electrochemical performances with a reversible capacity of 364.8 mAh·g-1, an irreversible capacity of 47.4 mAh·g-1, and an initial coulombic efficiency of 88.5%. The cycling stability of the Li/C cells with modified graphite as anodes was improved. The capacity retention ratio at the 30 th cycle was up to 91.97%.
Keywords: lithium ion battery  graphite  NaCl  anode
 
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周友元,李新海,郭华军,王志兴,杨勇,朱文明.氯化钠对锂离子电池石墨负极的修饰改性(英文)[J].无机化学学报,2007,23(2):353-356.
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