| 制备条件对SiO2改性氧化铝材料耐热性能的影响 |
| Influence of Preparation Conditions on Thermal Stability of Alumina Modified by SiO2 |
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| 摘要: |
| 关键词: 氧化铝 热稳定性 二氧化硅 |
| 基金项目: |
| Abstract: The thermal stabilization mechanism of silica and effect of preparation conditions on the thermal stability of silica-modified alumina have been investigated by low temperature nitrogen adsorption-desorption, XRD, TEM and 27Al MAS NMR. The results show that the addition of silica is effective in suppressing α phase transformation and therefore, in maintaining large surface area of alumina after heating at elevated temperatures. The stabilization effect of the silica species increases with the rise of silica content, however, the overabundance of silica species weakens its stabilization effect. The preparation conditions influence the thermal stability of alumina and stabilization effect of silica. Employing solgel and supercritical drying methods, silica-doped alumina materials with high thermal stability were prepared using NaAlO2 and water-soluble sodium silicate. |
| Keywords: alumina, thermal stability, silica |
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| 摘要点击次数: 1085 |
| 全文下载次数: 1741 |
| 岳宝华,周仁贤,郑小明.制备条件对SiO2改性氧化铝材料耐热性能的影响[J].无机化学学报,2007,23(3):533-536. |
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